Here you find our publications from the last years.

66
J. Warneke: Gas-Phase Ion Chemistry of [B12X12]2− (X = F, Cl, Br, I, CN).
A brief review of twelve years of researching twelve−vertexed dianions and their fragments
Int. J. Mass Spectrom. 2023, DOI: 10.1016/j.ijms.2023.117169

65

F. Yang, R. Urban, J. Lorenz, J. Griebel, N. Koohbor, M. Rohdenburg, H. Knorke, D. Fuhrmann, A. Charvat, B. Abel, V.A. Azov, J. Warneke:
Control of Intermediates and Products by Combining Droplet Reactions and Ion Soft-Landing
Angew. Chem. Int. Ed. 2023, DOI: 10.1002/ange.202314784

64
S. Kawa, H. Knorke, J. Jin, M. Rohdenburg, K.R. Asmis, R. Tonner-Zech, E. Bernhardt, C. Jenne, M. Finze, J. Warneke:
Binding properties of small electrophilic anions [B6X5] and [B10X9] (X = Cl, Br, I): Activation of small molecules based on π-backbonding.
Chem. Eur. J. 2023, DOI : 10.1002/chem.202302247.

63
M. Rohdenburg, Z. Warneke, H. Knorke, M. Icker, J. Warneke:
Chemical Synthesis with Gaseous Molecular Ions: Harvesting [B12Br11N2] From a Mass Spectrometer.
Angew. Chem. Int. Ed. 2023, accepted article, DOI: 10.1002/anie.202308600.
VIP article, Inside Cover

62
K. Yu. Monakhov, M. Moors, E. Vogelsberg; J. Lorenz; J. Warneke; F. Yang:
Solution-Processable Molecular Oxides for Integrated Memories.
Conference proceeding IEEE 2023, DOI: 10.1109/IITC/MAM57687

61
P. Su, Z. Warneke, D. Volke, M. F. Espenship, H. Hu, S. Kawa, K. Kirakci, R. Hoffmann, J. Laskin, C. Wiebeler, J. Warneke:
Gas Phase Reactivity of [Mo6X14]2− Dianions (X = Cl − I).
 J. Am. Soc. Mass Spectrom. 2023, 34, 161–170. DOI: 10.1021/jasms.2c00243

60
I. Werner, J. Griebel, A. Masip-Sánchez, X. López, K. Załęski, P. Kozłowski, A. Kahnt, M. Boerner, Z. Warneke, J. Warneke, K. Yu. Monakhov
Hybrid Molecular Magnets with Lanthanide- and Countercation-Mediated Interfacial Electron Transfer between Phthalocyanine and Polyoxovanadate.
Inorg. Chem. 2023, 62, 3761–3775. DOI: 10.1021/acs.inorgchem.2c03599.

61
P. Su, Z. Warneke, D. Volke, M. F. Espenship, H. Hu, S. Kawa, K. Kirakci, R. Hoffmann, J. Laskin, C. Wiebeler, J. Warneke:
Gas Phase Reactivity of [Mo6X14]2− Dianions (X = Cl − I).
J. Am. Soc. Mass Spectrom. 2022, DOI: 10.1021/jasms.2c00243.

60
I. Werner, J. Griebel, A. Masip-Sánchez, X. López, K. Załęski, P. Kozłowski, A. Kahnt, M. Boerner, Z. Warneke, J. Warneke, K. Yu. Monakhov:
Hybrid Molecular Magnets with Lanthanide- and Countercation-Mediated Interfacial Electron Transfer between Phthalocyanine and Polyoxovanadate
Inorg. Chem. 2022, DOI: 10.1021/acs.inorgchem.2c03599

59
F. Yang, M. Moors, D. A. Hoang, S. Schmitz, M. Rohdenburg, H. Knorke, A. Charvat, X.-B. Wang, K. Yu Monakhov, J. Warneke:
On-Surface Single-Molecule Identification of Mass-Selected Cyclodextrin-Supported Polyoxovanadates for Multistate Resistive-Switching Memory Applications.
ACS Appl. Nano Mater. 2022, 5, 14216–14220. DOI: 10.1021/acsanm.2c03025.

58
X. Ma, M. Rohdenburg, H. Knorke, S. Kawa, J. K. Y. Liu, E. Aprà, K. R. Asmis, V. A. Azov, J. Laskin, C. Jenne, H. I. Kenttämaa, J. Warneke:
Binding of saturated and unsaturated C6-hydrocarbons to the electrophilic anion [B12Br11]: a systematic mechanistic study.
Phys. Chem. Chem. Phys., 2022, 24, 21759–21772. DOI: 10.1039/D2CP01042A.

57

J. Warneke, H. Knorke, A. Charvat, K.G. Warneke:
Ion soft-landing of permanently charged molecular ions and their charge retention on surfaces.
Encyclopedia of Inorganic and Bioinorganic Chemistry, published in 2022, John Wiley & Sons (eibc2750). DOI

56
Q. Yuan, M. Rohdenburg, W. Cao, E. Apra, J. Landmann, M. Finze, J. Warneke, X.-B. Wang:
[B2(CN)6]2-: Small Yet Exceptionally Stable Nonmetal Dianion.
J. Phys. Chem. Lett. 2021, 12, 12005–12011. DOI

55
H. Y. Samayoa-Oviedo, K.-A. Behrend, S. Kawa, H. Knorke, P. Su, M. E. Belov, G. Anderson, J. Warneke, J. Laskin:
Design and Performance of a Soft-Landing Instrument for Fragment Ion Deposition.
Anal. Chem. 2021, 93, 14489-14496. DOI

54
F. Yang, K. A. Behrend, H. Knorke, M. Rohdenburg, A. Charvat, C. Jenne, B. Abel, J. Warneke:
Anion-Anion Chemistry with Mass-Selected Molecular Fragments on Surfaces.
Angew. Chem. Int. Ed. 2021, 24910-24914. DOI

53
T. Wulf, J. Warneke, T. Heine:
B12X11(H2): exploring the limits of isotopologue selectivity of hydrogen adsorption.
RSC Adv. 2021, 11, 28466-28475. DOI

52
M. Moors, J. Warneke, X. López, C. de Graaf, B. Abel, K. Yu. Monakhov:
Insights from Adsorption and Electron Modification Studies of Polyoxometalates on Surfaces for Molecular Memory Applications.
Acc. Chem. Res. 2021, DOI

51
J. Warneke, X.-B. Wang:
Measuring Electronic Structure of Multiply Charged Anions to Understand their Chemistry: A Case Study on Gaseous Polyhedral closo-Borate Dianions.
J. Phys. Chem. A 2021, 125, 6653–6661, DOI Invited perspective

50
K. Ueltzen, S. Schmitz, M. Moors, M. Glöß, M. Börner, I. Werner, Z. Warneke, J. Warneke, B. Abel, K. Yu. Monakhov:
Synthesis, Structure, and Surface Adsorption Characteristics of a Polynuclear MnII,IV–YbIII Complex
Inorg. Chem.  2021, DOI

49
M. Mayer, M. Rohdenburg, S. Kawa, F. Horn, H. Knorke, C. Jenne, R. Tonner, K. R. Asmis, J. Warneke:
Relevance of π-Backbonding for the Reactivity of Electrophilic Anions [B12X11] (X=F, Cl, Br, I, CN).
Chem. Eur. J.  2021, DOI

48
Y. Jiang, Q. Yuan, W Cao, M. Rohdenburg, M. C. Nierstenhöfer, Z. Li, Y. Yang, C. Zhong, C. Jenne, J. Warneke, H. Sun, Z. Sun, X.-B. Wang:
Gaseous cyclodextrin-closo-dodecaborate complexes χCD·B12X122− (χ = α, β, and γ; X = F, Cl, Br, and I): electronic structures and intramolecular interactions.
Phys. Chem. Chem. Phys. 2021, 23, 13447-13457, DOI.

47
R. Pütt, P. Kozłowski, I. Werner, J. Griebel, S. Schmitz, J. Warneke, K. Yu. Monakhov:
{P2V3W15}-Polyoxometalates Functionalized with Phthalocyaninato Y and Yb Moieties:
Inorg. Chem. 2021, 60, 80–86, DOI

46
H. Knorke, H. Li, J. Warneke, Z-F. Liu, K.A. Asmis: Cryogenic ion trap vibrational spectroscopy of the microhydrated sulfate dianions SO42−(H2O)3−8.  
Phys. Chem. Chem. Phys. Phys. 2020, 22, 27732-27745, DOI

45
M. Rohdenburg, V.A. Azov, J. Warneke:
New Perspectives in the Noble Gas Chemistry Opened by Electrophilic Anions:  
Front. Chem. 2020, 8, DOI.

44
Asmis, K.R., Beele, B., Jenne, C., Kawa, S., Knorke H., Nierstenhöfer, M.C., Wang, X., Warneke, J., Warneke, Z., Yuan, Q:
Synthesis, Electronic Properties and Reactivity of [B12X11(NO2)]2− (X=F–I) Dianions
Chem. Eur. J. 2020, 26, 14594-14601, DOI

43
J. Warneke, M. Mayer, M. Rohdenburg, X. Ma, Judy K.Y. Liu, M. Grellmann, S. Debnath, V. A., Azov, E. Apra, R. P. Young, C. Jenne, G.E. Johnson, H.I. Kenttämaa, K.R. Asmis, J. Laskin:
Direct functionalization of C−H bonds by electrophilic anions
Proc. Natl. Acad. Sci. U.S.A. 2020, 117, 23374-23379, DOI

42
M. Rohdenburg, Z. Yang, P. Su, E. Bernhardt, Q. Yuan, E. Apra, S. Grabowsky, J. Laskin, C. Jenne, X.-B. Wang, J. Warneke:
Properties of gaseous closo-[B6X6]2− dianions (X = Cl, Br, I).
Phys. Chem. Chem. Phys., 2020, 22, 17713-17724, DOI

41
M. Mayer, M. Rohdenburg, V. van Lessen, M. C. Nierstenhöfer, E. Aprà, S. Grabowsky, K. R. Asmis, C. Jenne, J. Warneke:
First steps towards a stable neon compound: observation and bonding analysis of [B12(CN)11Ne].
Chem. Commun., 2020, 56, 4591-4594, DOI
Chemistry world reports on this article

40
Z. Li, Y. Jiang, Q. Yuan, J. Warneke, Z. Hu, Y. Yang, H. Sun, Z. Sun X.-B. Wang:
Photoelectron spectroscopy and computational investigations of the electronic structures and noncovalent interactions of cyclodextrin-closo-dodecaborate anion complexes χ-CD·B12X122− (χ =α, β, γ; X = H, F).
Phys. Chem. Chem. Phys., 2020, 22, 7193-7200, DOI

39
R.-Z. Li, Q. Yuan, Z. Yang, E. Aprà, Z. Li, V. A. Azov, K. Kirakci, J. Warneke, X.-B. Wang:
Photoelectron spectroscopy of [Mo6X14]2− dianions (X = Cl–I).
J. Chem. Phys. 2019, 151, 194310, DOI

38
P. Su, A.J. Smith, J. Warneke, J. Laskin:
Gas-Phase Fragmentation of Host-Guest Complexes of Cyclodextrins and Polyoxometalates
J. Am. Soc. Mass Spectrom. 2019, 30, 1934-1945, DOI

37
P. Su, H. Hu, J. Warneke, M.E. Belov, G.A. Anderson, J. Laskin:
Design and Performance of a Dual-Polarity Instrument for Ion Soft Landing.
Anal. Chem. 2019, 91, 5904-5912, DOI

36
M. Mayer, V. van Lesse, M. Rohdenburg, G.-L. Hou, Z. Yang, R. M. Exner, E. Aprà, V. A. Azov, S. Grabowsky, S. S. Xantheas, K. R. Asmis, X.-B. Wang, C. Jenne, J. Warneke:
Rational design of an argon-binding superelectrophilic anion.
Proc. Natl. Acad. Sci. U.S.A 2019, 116, 8167-8172, DOI

35
E. Aprà, J. Warneke, S.S Xantheas, X.-B. Wang:
A benchmark photoelectron spectroscopic and theoretical study of the electronic stability of [B12H12]2-.
J. Chem. Phys. 2019, 150, 164306. DOI

34
P. J. J. Carr, J. Warneke, J. Featherstone, C. Jenne, E. Loire, W. S. Hopkins:
The structure of proton-bound Triethylammonia B12X122− (X = F, Cl) Clusters
Mol. Phys. 2019, 117, 2972-2979, DOI

33
L. A. Bischoff, M. Drisch, C. Kerpen, P. T. Hennig, J. Landmann, J. A. P. Sprenger, R. Bertermann, M. Grüne, Q. Yuan, J. Warneke, X.-B. Wang, N. Ignat'ev, M. Finze:
Cyanohydridoborate Anions: Synthesis, Salts, and Low‐viscosity Ionic Liquids
Chem. Eur. J. 2019, 25, 3560-3574, DOI

32
J. Warneke, S. Z. Konieczka, G.-L. Hou, E. Aprà, C. Kerpen, F. Keppner, T. C. Schäfer, M. Deckert, Z. Yang, E. Bylaska, G. E. Johnson, J. Laskin, S. S. Xantheas, X.-B. Wang, M. Finze:
Properties of perhalogenated {closo-B10} and {closo-B11} multiply charged anions and a critical comparison with {closo-B12} in the gas and condensed phases,
Phys. Chem. Chem. Phys. 2019, 21, 5903-5915. Back cover, DOI

31
J. Warneke, M. Rohdenburg, J. K.Y. Liu, E. Johnson, X. Ma, R. Kumar, P. Su, E. Aprà, X.-B. Wang, C. Jenne, M. Finze, H. I. Kenttämaa, J. Laskin:
Gas Phase Fragmentation of Adducts between Dioxygen and closo-Borate Radical Anions
Int. J. Mass Spectrom 2019, 436, 71-78. Special issue in honor of Helmut Schwarz, DOI

30
J. Laskin, G. E. Johnson, J. Warneke, V. Prabhakaran:
From Isolated Ions to Multilayer Functional Materials Using Ion Soft-Landing
Angew. Chem. Int. Ed. 2018, 57, 16270-16284, DOI.

29
J. Warneke, M. E. McBriarty, S. L. Riechers, S. China, M. H. Engelhard, E. Aprà, R. P. Young, N. M. Washton, C. Jenne, G. E. Johnson, J. Laskin:
Self-organizing layers from complex molecular anions
Nat. Commun. 2018, 9, 1889, DOI
Featured on the Editors’ Highlights webpage

28
Z. Warneke, M. Rohdenburg, J. Warneke, J. Kopyra, P. Swiderek:
Electron-driven and thermal chemistry during water-assisted purification of platinum nanomaterials generated by electron beam induced deposition
Beilstein J. Nanotechnol. 2018, 9, 77 – 90, DOI

27
J. Warneke, G.-L. Hou, E. Aprà, C. Jenne, Z. Yang, Z. Qin, K. Kowalski, X.-B. Wang, S. S. Xantheas:
Electronic Structure and Stability of [B12X12]2- (X=F−At): A Combined Photoelectron Spectroscopic and Theoretical Study
J. Am. Chem. Soc. 2017, 139, 14749 – 14756, DOI

26
M. Rohdenburg, M. Mayer, M. Grellmann, C. Jenne, T. Borrmann, F. Klemiss, V. A. Azov, K. R. Asmis, S. Grabowsky, J. Warneke:
Superelectrophilic Behavior of an Anion Demonstrated by the Spontaneous Binding of Noble Gases to [B12Cl11]-
Angew. Chem. Int. Ed. 2017, 56, 7980 – 7985, DOI

25
T. Weiss, J. Warneke, V. Zielasek, P. Swiderek, M. Bäumer:
XPS study of thermal and electron-induced decomposition of Ni and Co acetylacetonate thin films for metal deposition;
J. Vac. Sci. Technol. A 2016, 34, 041515, DOI

24
J. Kopyra, C. König-Lehmann, E. Illenberger, J. Warneke, P. Swiderek:
Low energy electron induced reactions in fluorinated acetamide – probing negative ions and neutral stable counterparts;
Eur. Phys. J. D. 2016, 70, 140, DOI

23
J. Warneke, C. Jenne, J. Bernarding, V.A. Azov, M. Plaumann:
Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets;
Chem. Commun., 2016, 52, 6300 – 6303, DOI

22
J. Warneke, T. Dülcks, D. Kemken and M. Finze:
Identification of a neutral loss from precursor ions with nearly Gaussian-shaped isotopic patterns via inverted isotopic patterns of product ions;
Rapid Commun. Mass Spectrom. 2016, 30, 985–991, DOI

21
J. Warneke, M. Rohdenburg, Y. Zhang, J. Orzagh, A. Vaz, I. Utke, J. Th. M. De Hosson, W. F. van Dorp, P. Swiderek:
Role of NH3 in the Electron-Induced Reactions of Adsorbed and Solid Cisplatin;
J. Phys. Chem. C, 2016, 120, 4112–4120, DOI

20
I. Schrader, S. Neumann , R. Himstedt , A. Zana, J. Warneke, S. Kunz:
The Effect of Particle Size and Ligand Configuration on the Asymmetric Catalytic Properties of Proline-functionalized Pt-Nanoparticles;
Chem. Commun., 2015, 51, 16221-16224, DOI

19
T. Svoboda, J. Warneke, A. Růžička, L. Dostál, J. Beckmann:
Synthesis and structure of heavy group 15 metallastannoxanes [2,6-(Me2NCH2)2C6H3E](2,6-Mes2C6H3Sn)3O3(OH)5 (E = Sb, Bi);
J. Organomet. Chem. 2015, 797, 171-173., DOI

18
I. Schrader, J. Warneke, S. Neumann, S. Grotheer, A. Abildgaard Swane, J. J. K. Kirkensgaard, M. Arenz, S. Kunz:
Surface Chemistry of “Unprotected” Nanoparticles: A Spectroscopic Investigation on Colloidal Particles;
J. Phys. Chem. C 2015, 119, 17655-17661, DOI

17
J. Warneke, P. Swiderek:
Electron-induced decomposition of condensed acetone studied by quantifying desorption and retention of volatile products;
J. Phys. Chem. C 2015, 119, 8725-8735, DOI

16
M.R. Fagiani, L.L. Zeonjuk, T.K. Esser, D. Gabel, T. Heine, K.R. Asmis, J. Warneke:
Opening of an Icosahedral Boron Framework: A Combined Infrared Spectroscopic and Computational Study;
Chem. Phys. Lett. 2015, 625, 48-52. Editor’s Choice article DOI

15
C. Jenne, M. Keßler, J. Warneke:
Protic anions [H(B12X12)]- (X = F-I) that act as Brønsted acids in the gas phase;
Chem. Eur. J. 2015, 21, 5887-5891, DOI

14
E. Moosbach, M. Nesselberger, J. Warneke, P. Harz, M. Arenz, M. Bäumer, S. Kunz: 1-Naphthylamine functionalized Pt nanoparticles: Electrochemical activity and redox chemistry occurring on one surface;
New J. Chem. 2015, 39, 2557-2564, DOI

13
J. Warneke, M. Plaumann, Z. Wang, E. Böhler, D. Kemken, S. Kelm, D. Leibfritz, V.A. Azov:
New insights into the old reaction between acryloyl chlorides and pyridine;
Tetrahedron Lett. 2015, 56, 1124-1127, DOI

12
J. Warneke, Z. Wang, P. Swiderek, J.H. Bredehöft: Electron-Induced Hydration of an Alkene: Alternative Reaction Pathways;
Angew. Chem. Int. Ed. 2015, 54, 4397-4400, DOI

11
A. Himmelspach, J. Warneke, M. Schäfer, M. Hailmann, M. Finze:
Salts of the Dianions [Hg(12-X-closo-1-CB11H10)2]2– (X = I, C≡CH, C≡CFc, C≡CSiiPr3): Synthesis and Spectroscopic and Structural Characterization;
Organometallics 2015, 34, 462-469, DOI

10
I. Schrader, J. Warneke, J. Backenköhler, S. Kunz:
Functionalization of Platinum Nanoparticles with L-Proline: Simultaneous Enhancements of Catalytic Activity and Selectivity;
J. Am. Chem. Soc. 2015, 137, 905-912, DOI

9
J. Warneke, W.F. Van Dorp, P. Rudolf, M. Stano, P. Papp, Š. Matejčík, T. Borrmann, P. Swiderek:
Acetone and the precursor ligand acetylacetone: Distinctly different electron beam induced decomposition?;
Phys. Chem. Chem. Phys. 2015, 17, 1204-1216, DOI

8
M. Zeller, J. Warneke, V. Azov:
Relative substituent orientation in the structure of cis-3-chloro-1,3-dimethyl-N-(4-nitrophenyl)-2-oxocyclopentane-1-carboxamide;
Acta Cryst., 2014 E70, 121-123, DOI

7
J. Warneke, Z. Wang, M. Zeller, D. Leibfritz, M. Plaumann, V. A. Azov:
Methacryloyl chloride dimers: from structure elucidation to a manifold of chemical transformations;
Tetrahedron 2014, 70, 6515-6521, DOI
Alfa Aesar changed official product description based on these results, (Link)

6
R.T. Boeré, J. Derendorf, C. Jenne, S. Kacprzak, M. Keßler, R. Riebau, S. Riedel, T.L. Roemmele, M. Rühle, H. Scherer, T. Vent-Schmidt, J. Warneke, S. Weber:
On the Oxidation of the Three-Dimensional Aromatics [B12X12]2− (X = F,Cl,Br,I);
Chem. Eur. J. 2014, 20, 4447-4459, DOI

5
E. Böhler, J. Warneke, P. Swiderek:
Control of chemical reactions and synthesis by low-energy electrons;
Chem. Soc. Rev. 2013, 42, 9219-9231, DOI
Inside front cover, Issue 24

4
P. Farràs, N. Vankova, L. L. Zeonjuk, J. Warneke, T. Dülcks, T. Heine, C. Viñas, F. Teixidor, D. Gabel: From an Icosahedron to a Plane:
Flattening Dodecaiodododecaborate by Successive Stripping of Iodine;
Chem. Eur. J. 2012, 18, 13208-13212, DOI

3
A. Himmelspach, J. A. P. Sprenger, J. Warneke, M. Zähres, M. Finze:
Mercury(II) Complexes of the Carba-closo-dodecaboranyl Ligands [closo − 1 − CB11X11]2- (X = H, F,Cl,B, I);
Organometallics 2012, 31, 1566-1577, DOI

2
J. Warneke, T. Dülcks, C. Knapp, D. Gabel:
Collision-induced gas-phase reactions of perhalogenated closo-dodecaborate clusters - a comparative study;
Phys. Chem. Chem. Phys. 2011, 13, 5712-5721, DOI

1
C. Bolli, J. Derendorf, M. Keßler, C. Knapp, H. Scherer, C. Schulz, J. Warneke:
Synthesis, Crystal Structure, and Reactivity of the Strong Methylating Agent Me2B12Cl12;
Angew. Chem. Int. Ed. 2010, 49, 3536-3538, DOI
This article was listed by John Wiley & Sons under “Hottest articles in Organic Chemistry” 2010  

Thesis (Completed Master- und Bachelorarbeiten and Extended Lab Courses)

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